Researchers convert plastic bags into a variety of petroleum products

Despite efforts to limit their use through implementation of charges or bans, billions of plastic bags continue to clog landfills, waterways and the world’s oceans every year. Already a potential source for carbon fiber and carbon nanotubes, researchers have provided another reason not to throw the ubiquitous bags away by converting them into a range of petroleum products.
The researchers from the Illinois Sustainable Technology Center (ISTC) at the University of Illinois used a process known as pyrolysis, which involves heating the plastic bags in an oxygen-free chamber. Although this technique has been used by other research teams to convert plastic bags back into crude oil (which they are originally produced from) the U of I team went the next step and fractionated the crude oil into different petroleum products.
In this way, the researchers were able to produce natural gas, naphtha, gasoline, waxes, and lubricating oils, such as engine oil and hydraulic oil. They also produced diesel that can be blended with existing ultra-low-sulfur diesels and biodiesels, which the team tested for compliance with US standards.
“A mixture of two distillate fractions, providing an equivalent of U.S. diesel #2, met all of the specifications required of other diesel fuels in use today – after addition of an antioxidant,” said Brajendra Kumar Sharma, a senior research scientist at the ISTC. “This diesel mixture had an equivalent energy content, a higher cetane number (a measure of the combustion quality of diesel requiring compression ignition) and better lubricity than ultra-low-sulfur diesel.”
The team blended up to 30 percent of the plastic bag-derived diesel into regular diesel with no problems and found no compatibility issues with biodiesel.
“It’s perfect,” said Sharma. “We can just use it as a drop-in fuel in the ultra-low-sulfur diesel without the need for any changes.”
Sharma says the conversion process also produces significantly more energy than it uses. “You can get only 50 to 55 percent fuel from the distillation of petroleum crude oil,” he said. “But since this plastic is made from petroleum in the first place, we can recover almost 80 percent fuel from it through distillation.”
The team’s study appears in the journal Fuel Processing Technology.

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Could moly sulfide be the key to cheaper hydrogen production?

Chemical engineers have found a 30-year-old recipe that stands to make future hydrogen production cheaper and greener. The recipe has led researchers to a way to liberate hydrogen from water via electrolysis using molybdenum sulfide – moly sulfide for short – as the catalyst in place of the expensive metal platinum.
While hydrogen is relatively abundant here on Earth, it is generally bound to either carbon or oxygen to form methane and water respectively. Producing hydrogen currently involves liberating it from methane at a cost of between US$1 and $2 per kilogram. And the world’s hunger for hydrogen continues to grow, currently we consume 55 billion kilograms of the element per year, making freeing it from methane or water big business. And with numerous automakers dipping their tires in the hydrogen fuel waters, it’s set to get much bigger.
The other side of the equation is the by-product of production. When hydrogen is freed from methane the waste product is carbon, which is released into the atmosphere furthering climate change. Producing hydrogen from water on the other hand produces oxygen as waste.
The limiting factor to getting hydrogen from water in the past has been the expense of electrolysis, the process were hydrogen atoms are liberated from their bond with oxygen in water by passing an electrical current through an electrode immersed in the water. The main expense in this process was the use of platinum as the electrode. The efficiency of platinum to catalyze the breaking of hydrogen-oxygen bonds in water to free the hydrogen until now has been unmatched.
Enter moly sulfide. Since World War II, moly sulfide has been used by petroleum engineers in the refinement of oil. It was thought to be inefficient for the electrolysis of hydrogen from water due to the molecular structure at its surface.
That was until Stanford Engineering’s Jens Nørskov, then at the Technical University of Denmark, noticed this structure differed at the edges of the crystal lattice. Around the edges, hydrogen production was possible as the structure has only two chemical bonds rather than the three seen elsewhere in its structure. This meant moly sulfide was capable of electrolyzing hydrogen, if only at the edges.
Next came the Eureka moment, when the researchers uncovered a 30-year-old recipe for double bonded moly sulfide. Using this recipe, nanoclusters of double-bonded moly sulfide were synthesized and deposited on an electrically conductive sheet of graphite to form a cheap electrode alternative to platinum.
Initial tests show the new technology to work at an efficiency approaching that of platinum. Early cost predictions for factory-scale production range from $1.60 to $10.40, which at the lower end would be competitive with current methane-based methods.
“There are many pieces of the puzzle still needed to make this work and much effort ahead to realize them,” said Stanford Engineering Assistant Professor Thomas Jaramillo. “However, we can get huge returns by moving from carbon-intensive resources to renewable, sustainable technologies to produce the chemicals we need for food and energy.”
Findings of the research, which is a collaboration between Stanford University and Aarhus University in Denmark, were published in Nature Chemistry .

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Scientists create an inexpensive self-healing polymer

Stretchy, self-healing paints and other coatings recently took a step closer to common use, thanks to research being conducted at the University of Illinois. Scientists there have used “off-the-shelf” components to create a polymer that melds back together after being cut in half, without the addition of catalysts or other chemicals.

The material is made from a proprietary mixture of inexpensive commercially-available compounds, including a polyurea elastomer – polyurea is commonly found in a wide variety of products such as paints and plastics. The researchers reportedly “tweaked” the structure of its molecules, making the bonds between them longer. As a result, the molecules are easier to pull apart from one another, but they’re also better able to bond back together.
When samples of what is being called “dynamic polyurea” are cut and then left for a day with the severed ends touching, they will heal back together with almost the same strength that they had before cutting. The process works at room temperature, although raising the ambient temperature to 37ºC (98.6ºF) will speed it up.
Some other experimental self-healing materials incorporate liquid-filled micro-capsules that break open when the material is cut or cracked. This means that they will only heal as long as there are unruptured capsules present. By contrast, dynamic polyurea can reportedly heal over and over again, as it relies solely on its molecular structure.
A paper on the research was recently published in the journal Nature Communications.
Source: University of Illinois

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Scientists use fruit flies to detect cancer

Scientists from the University of Konstanz, Germany, are the first to demonstrate that fruit flies can distinguish cancerous cells from healthy ones via their sense of smell. The team has genetically modified fruit flies so that their antennae glow when they detect a cancerous odor. In an experiment, scientists directed smells at fruit flies. The fruit flies’ appearance was monitored via a microscope.
Cancer cells and normal cells emit slightly different odors due to their metabolic differences. Dogs and bees have both previously been shown to be capable of detecting cancerous cells. The Konstanz research looked at whether fruit flies, with their sensitive sense of smell, could do the same. In finding that this was indeed the case, the research focused on modifying receptor cells on the fruit flies’ antennae to glow when a cancerous odor was detected.
Most olfactory receptor neurons have a specific olfactory receptor type, but the receptor neurons of fruit flies have about 50 different types of receptor. Different odors cause a different response in the receptor neurons, and the scientists were able to modify the relevant neurons so that a response triggered by a cancerous odor caused a fluorescent protein therein to glow.
“What really is new and spectacular about this result is the combination of objective, specific and quantifiable laboratory results and the extremely high sensitivity of a living being that cannot be matched by electronic noses or gas chromatography”, says Giovanni Galizia, who led the project.
According to the the research, not only were cancer cells able to be told apart from healthy cells, but even different types of cancer cells were able to be differentiated via the fruit flies’ antennae. Galizia hopes that the research can be used to accelerate the process of creating devices that can detect cancer quickly and non-invasively.
“The high sensitivity of the natural olfactory receptors, paired with the quickness with which we can generate these test results, might lead to the development of a cheap, fast and highly-efficient pre-screening that can detect cancer cells well before we can discover them with the present diagnostic imaging techniques,” he explains.

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Distant quasar lights up cosmic web like a neon sign

That the Universe is largely composed of a cosmic web consisting of narrow filaments upon which galaxies and intergalactic gas and dust are concentrated has been known for more than a decade. While a great deal of evidence for this has accumulated, visual evidence has been difficult to find. Astronomers have now photographed what appears to be a segment of a cosmic filament stimulated into fluorescence by irradiation from a nearby quasar.



That the Universe is largely composed of a cosmic web consisting of narrow filaments upon which galaxies and intergalactic gas and dust are concentrated has been known for more than a decade. While a great deal of evidence for this has accumulated, visual evidence has been difficult to find. Astronomers have now photographed what appears to be a segment of a cosmic filament stimulated into fluorescence by irradiation from a nearby quasar.

The filaments of the cosmic web are difficult to see visually. They consist primarily of dark matter and intergalactic gas and dust, none of which have a visible signature detectable across billions of light years. As a result, our knowledge of filaments primarily comes from gravitational lensing studies, radio observations, and x-ray telescopes.
Now a team, led by researchers at the University of California, Santa Cruz (UCSC), has found an unusual configuration of celestial objects that appears to make visible a part of a filament that is ten billion light years distant. The section of the filament that is visible takes the form of a huge asymmetric nebula of diffuse intergalactic gas.
Normally this gas would not emit significant amounts of light, but in this case the intergalactic gas is being irradiated by extreme UV light from a nearby quasar; the active center of a galaxy. This irradiation ionized the gas (mostly consisting of atomic hydrogen), which then emits the characteristic light of atomic hydrogen (Lyman-alpha radiation) when the ionized atoms regain their electrons. When redshift (z~2.27) is taken into account, the Lyman-alpha radiation appears to our instruments as a violet glow, as seen in the lead photograph.
Let’s start by taking a look at the observational evidence for a web of cosmic filaments in the Universe. (A cosmic web also appears in simulations of the evolution of the Universe, but data are better than simulations any time.)
The astrophoto shown above is of a huge and nearly one-dimensional cluster of galaxies that was found by the Sloan Digital Sky Survey (SDSS) along a cosmic filament.
The map above is also a product of the SDSS, which used a 2.5 meter telescope to image and determine redshift (and thereby distance) for galaxies in the cosmic vicinity of the Milky Way galaxy. It includes galaxies and quasars located in a thin slice of the sky above the Earth’s equator out to a distance of two billion light years. One’s first impression is of a slice through a foam of luminous bodies that lay on the boundary of huge voids.
Rather solid evidence also exists for the existence of filaments with a goodly share of dark matter, as illustrated in the above figure of just such adark matter filament. This filament stretches about sixty million light years between the galaxy clusters Abell 222 and 223. X-ray emissions from the filament suggest that nearly 10 percent of the filament’s mass consists of hot gas. This filament comprises at least dark matter and intergalactic gas.
The team published a report in the January 19 issue of Nature of their discovery of a rather unusual configuration of celestial objects in the early history of the Universe (about three billion years after the Big Bang) that provides additional evidence for the existence of the cosmic web. The lead photo is an astrophoto, taken in redshifted Lyman-alpha radiation from hydrogen gas using the 10-meter Keck I telescope in Hawaii. It shows a distant (z~2.27) quasar named UM 287 that appears to be surrounded by a glowing nebula of diffuse gas. However, this is no ordinary nebula.
The above map of the region surrounding the nebula appears to show no object near the nebula that could cause it to be excited into fluorescence other than UM 287. (The small quasar at approximately the same distance as UM 287 is far too dim to light up this nebula.)
Taking as a hypothesis that UM 287 and the nebula are at the same distance, the researchers were able to test the idea. The figure above shows the neighborhood of UM 287 taken on the left in redshifted hydrogen (Lyman-alpha) light, and on the right in a broad range of wavelengths that excludes redshifted hydrogen emissions. That the nebula appears in the redshifted Lyman-alpha light on the left image and not on the right tells us that the nebular light is line emission; specifically hydrogen emissions, and that the redshift of the nebula and the quasar are essentially identical.
The difference in the Lyman-alpha and broad spectrum images allowed the team to subtract out the background radiation, giving the above detailed image of the nebula including only the Lyman-alpha emissions. The purported filament, while far smaller than that observed between Abell 222 and 223, is much clearer in this view.
The nebula is about a minute of arc across in the photograph. (It may actually be much larger, if it extends beyond the quasar’s ability to make the nebular gas fluoresce.) Using the standard cosmological model to trace back through the expanding spacetime to that period in the distant past, the size of the nebula is about 1.5 MLy (million light years). This is larger than any previously known Lyman-alpha source, leading to the question of just what the nebula might be.
Indeed, the extent of the nebula is too large to be gas gravitationally trapped by the quasar, even taking into account the quasar’s halo of dark matter. UM 287 is a radio-quiet quasar, and such quasars with luminosity equal to that of UM 287 have never been seen to have such extensive halos. Such a halo would have a mass over ten times larger than the largest known quasar halo.
So large a halo causes clumping of the matter contained therein, and observationally this appears as a high density of localized Lyman-alpha sources. The level of clumping observed around UM 287 also indicates a much smaller halo, in all likelihood extending no more than 300 thousand light years or so. The evidence supports that the nebula found in the region surrounding UM 287 is formed of intergalactic gas.
“We have studied other quasars this way without detecting such extended gas,” said Dr. Sebastiano Cantalupo, a member of the UCSC team. “The light from the quasar is like a flashlight beam, and in this case we were lucky that the flashlight is pointing toward the nebula and making the gas glow. We think this is part of a filament that may be even more extended than this, but we only see the part of the filament that is illuminated by the beamed emission from the quasar.”
So how much gas did they find? Any hydrogen atoms that can emit Lyman-alpha radiation must be cool enough to recapture their electrons once ionized, as this recapture is what generates the radiation. This calls for a temperature smaller than about 50,000 K. At larger temperatures, the electrons have too much energy to be captured, so “hot” gas does not add to the observed nebular emissions; we can only see cold hydrogen.
The researchers estimated the amount of gas in the nebula based on the ability of the quasar’s radiation to penetrate the nebular gas and then to effectively stimulate an hydrogen atom to emit a Lyman-alpha photon. These estimates included two extreme cases as shown above, if all the nebular gas is ionized (left), and if none of the nebular gas is ionized (right). In both cases, the mass of the filament is found to be about a trillion solar masses.
This mass is at least ten times more than indicated by computer simulations of the Universe’s evolution, and the filamental web that results. It is somewhat embarrassing; if the entire cosmic web were ten times more massive than expected, the Universe would have too much mass to be in its current configuration.
There are at least four explanations for this discrepancy. Obviously, and perhaps most likely, the simulation may not include all the physical mechanisms required to accurately model the details of the filaments.
Another limitation of the simulation is that it has a smallest size of about 30,000 light years, which is similar to the optical resolution of these observations. The amount of gas required to explain the observations of UM 287’s nebula becomes smaller if that gas is concentrated into clumps of higher density. If such clumps do evolve and are typically smaller than, say, 10,000 light years, the observations would not detect them, and the simulations would not reproduce them. However, the clumping needs to be rather extreme to reconcile the observations with the filament simulation.
Third, the particular region of the filament that is illuminated by the quasar might be atypically dense for some reason that is presently unknown. The study authors have done a good job of ruling out a past gravitational interaction between UM 287 and the dimmer quasar, which are at very nearly the same distance and are separated by less than some ten million light years.
Finally, the nebula may not be a cosmic filament at all. While it is tempting to make this identification, and most of the observational evidence is at least compatible with the conjecture, there is no smoking gun that converts this conjecture into a “most likely explanation”. Ideally, a smoking gun would allow one to argue backward from the observational data to conclude that a web of cosmic filaments exists. One observation of a configuration that is suggestive of being a filament doesn’t cut it.
In the end, the observations of the atypical nebula surrounding UM 287 reveal an unusual situation calling out for attempts to obtain more data and to seek out other examples of the phenomenon, but do not lead to the conclusion that the intergalactic gas in a filament has been observed. A reasonable conjecture? Yes, but nothing even close to a smoking gun. This will be an interesting story to follow.
Source: arXiv.org

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Super-tough glass based on mollusk shells

 
 
 
In the futureImage, if you drop a glass on the floor and it doesn’t break, thank a mollusk. Inspired by shellfish, scientists at Montreal’s McGill University have devised a new process that drastically increases the toughness of glass. When dropped, items made using the technology would be more likely to deform than to shatter.
If you look at the inside surface of the shell of a mollusk such as an abalone, mussel or oyster, you’ll see a shiny iridescent material. This is called nacre(also known as mother-of-pearl), and it’s what gives the shell its strength – the outer surface of the shell is made almost entirely of calcium carbonate, and would be very brittle on its own.
A team led by Prof. François Barthelat studied the internal structure of nacre, which is comprised of individual microscopic “tablets” that interlock in a fashion similar to Lego blocks. The researchers noticed that the boundaries between the tablets aren’t straight but instead are wavy, like the edges of jigsaw puzzle pieces.
The scientists replicated these boundaries in glass microscope slides, using lasers to engrave networks of wavy 3D “micro-cracks” within them. When the slides were subjected to an impact, the micro-cracks absorbed and dispersed the energy, keeping the glass from shattering. Altogether, the treated slides were reportedly 200 times tougher than slides which were not treated.
Barthelat believes that it would be relatively simple to scale the process up to larger sheets of glass, and is also planning on applying it to other brittle materials such as ceramics and polymers. A paper on the research was recently published in the journal Nature Communications.